Vol. 5, Issue 2, Part A (2023)

The phosphorus element having a polymeric nature and formed the macro-compounds or polymers. The phosphorus compounds such as the poly-(phosphates and phosphazenes) were shown the stereo-chemistry as optical-geometrical isomerism with chair-boat conformation and molecular symmetry (C3v, C2h and D3h) in their novel structure. The structure of these polymeric compounds have been characterized by IR, X-ray, Raman spectra and by 31P NMR analyses as well.